Calculate de Broglie wavelength of electron accelerated through 100V potential

easy CBSE JEE-MAIN JEE Main 2023 2 min read

Question

Calculate the de Broglie wavelength of an electron accelerated through a potential difference of 100V100\,\text{V}.

(JEE Main 2023, similar pattern)


Solution — Step by Step

When an electron (charge ee) is accelerated through potential VV:

KE=eV=1.6×1019×100=1.6×1017JKE = eV = 1.6 \times 10^{-19} \times 100 = 1.6 \times 10^{-17}\,\text{J}
KE=p22m    p=2mKEKE = \frac{p^2}{2m} \implies p = \sqrt{2mKE} p=2×9.1×1031×1.6×1017p = \sqrt{2 \times 9.1 \times 10^{-31} \times 1.6 \times 10^{-17}} =29.12×1048=5.396×1024kg m/s= \sqrt{29.12 \times 10^{-48}} = 5.396 \times 10^{-24}\,\text{kg m/s} λ=hp=6.63×10345.396×1024\lambda = \frac{h}{p} = \frac{6.63 \times 10^{-34}}{5.396 \times 10^{-24}} =1.228×1010m1.23A˚= 1.228 \times 10^{-10}\,\text{m} \approx \mathbf{1.23\,\text{\AA}}

Why This Works

De Broglie’s hypothesis says every moving particle has an associated wavelength λ=h/p\lambda = h/p. For an electron accelerated through voltage VV, the electric field gives it kinetic energy eVeV, which determines its momentum, which determines its wavelength.

The result λ1.23A˚\lambda \approx 1.23\,\text{\AA} for V=100VV = 100\,\text{V} is comparable to atomic spacings in crystals — which is why electron diffraction works and why the electron microscope is useful.


Alternative Method — Use the shortcut formula

For electrons accelerated through VV volts:

λ=12.27VA˚\lambda = \frac{12.27}{\sqrt{V}}\,\text{\AA} λ=12.27100=12.2710=1.227A˚\lambda = \frac{12.27}{\sqrt{100}} = \frac{12.27}{10} = 1.227\,\text{\AA}

This shortcut is derived from combining λ=h/2meV\lambda = h/\sqrt{2meV} with the known constants. It’s a massive time-saver in MCQs.

Memorise λ=12.27/V\lambda = 12.27/\sqrt{V} (in angstroms) for electrons. For JEE, this formula converts a 5-step calculation into a 1-step answer. Also remember: 1A˚=1010m=0.1nm1\,\text{\AA} = 10^{-10}\,\text{m} = 0.1\,\text{nm}.


Common Mistake

Students sometimes use the relativistic momentum formula for this problem. At V=100VV = 100\,\text{V}, the electron’s kinetic energy is 100eV100\,\text{eV}, which is tiny compared to its rest energy of 0.511MeV0.511\,\text{MeV}. The non-relativistic approximation is perfectly valid here. Relativistic corrections become necessary only above ~10kV10\,\text{kV} or so. Using the relativistic formula unnecessarily complicates the calculation for no gain in accuracy.

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