Surface tension — excess pressure inside a soap bubble and liquid drop

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Question

Derive the expression for excess pressure inside (a) a liquid drop and (b) a soap bubble. A soap bubble of radius 2 cm is formed. If the surface tension of the soap solution is 0.03 N/m, find the excess pressure inside the bubble.

(NEET 2022, similar pattern)


Solution — Step by Step

Excess pressure inside a liquid drop

A liquid drop has one surface (the outer surface in contact with air). Surface tension acts along this surface, trying to minimise the area. This inward pull creates an excess pressure inside.

Consider a spherical drop of radius RR with surface tension TT. Imagine cutting it in half. The surface tension force along the rim of the cut acts inward: Fsurface=T×2πRF_{surface} = T \times 2\pi R.

The pressure force pushing outward on the cross-section: Fpressure=ΔP×πR2F_{pressure} = \Delta P \times \pi R^2.

At equilibrium:

ΔP×πR2=T×2πR\Delta P \times \pi R^2 = T \times 2\pi R

ΔPdrop=2TR\boxed{\Delta P_{drop} = \frac{2T}{R}}

Excess pressure inside a soap bubble

A soap bubble has two surfaces — an inner surface and an outer surface (it's a thin film). Both surfaces contribute to the inward force.

The surface tension force is now doubled: Fsurface=2×T×2πR=4πRTF_{surface} = 2 \times T \times 2\pi R = 4\pi RT.

Equating with pressure force:

ΔP×πR2=4πRT\Delta P \times \pi R^2 = 4\pi RT

ΔPbubble=4TR\boxed{\Delta P_{bubble} = \frac{4T}{R}}

The factor of 4 (instead of 2) is because of the two free surfaces of the soap film.

Numerical calculation

Given: R=2R = 2 cm =0.02= 0.02 m, T=0.03T = 0.03 N/m

ΔP=4TR=4×0.030.02=0.120.02\Delta P = \frac{4T}{R} = \frac{4 \times 0.03}{0.02} = \frac{0.12}{0.02}

ΔP=6 Pa\boxed{\Delta P = 6 \text{ Pa}}


Why This Works

Surface tension is a force per unit length that acts along the surface of a liquid, always trying to minimise the surface area. For a curved surface, this inward pull creates a pressure difference — the concave side always has higher pressure.

The critical distinction: a liquid drop has one surface (liquid-air), giving 2T/R2T/R. A soap bubble has two surfaces (outer air-soap and inner soap-air), giving 4T/R4T/R. A bubble inside a liquid (like an air bubble in water) also has one surface, so it follows the 2T/R2T/R formula.


Alternative Method — Energy approach

For a soap bubble expanding by dRdR: work done by excess pressure = increase in surface energy.

ΔP×4πR2×dR=T×d(2×4πR2)=T×16πRdR\Delta P \times 4\pi R^2 \times dR = T \times d(2 \times 4\pi R^2) = T \times 16\pi R \, dR

ΔP=4TR\Delta P = \frac{4T}{R}

💡 Expert Tip

Quick memory aid: Drop = 2T/R, Bubble = 4T/R. The soap bubble formula has the extra factor of 2 because of two surfaces. If the question says "air bubble in water," use 2T/R2T/R (only one surface). NEET loves testing this distinction.


Common Mistake

⚠️ Common Mistake

The most common error: using 2T/R2T/R for a soap bubble. Students forget that a soap bubble is a thin film with two surfaces. A liquid drop in air has one surface (2T/R2T/R). A soap bubble in air has two surfaces (4T/R4T/R). An air bubble inside a liquid has one surface (2T/R2T/R). Always count the number of free surfaces before writing the formula.

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