Question
Derive the expression for excess pressure inside (a) a liquid drop and (b) a soap bubble. A soap bubble of radius 2 cm is formed. If the surface tension of the soap solution is 0.03 N/m, find the excess pressure inside the bubble.
(NEET 2022, similar pattern)
Solution — Step by Step
Excess pressure inside a liquid drop
A liquid drop has one surface (the outer surface in contact with air). Surface tension acts along this surface, trying to minimise the area. This inward pull creates an excess pressure inside.
Consider a spherical drop of radius with surface tension . Imagine cutting it in half. The surface tension force along the rim of the cut acts inward: .
The pressure force pushing outward on the cross-section: .
At equilibrium:
Excess pressure inside a soap bubble
A soap bubble has two surfaces — an inner surface and an outer surface (it's a thin film). Both surfaces contribute to the inward force.
The surface tension force is now doubled: .
Equating with pressure force:
The factor of 4 (instead of 2) is because of the two free surfaces of the soap film.
Numerical calculation
Given: cm m, N/m
Why This Works
Surface tension is a force per unit length that acts along the surface of a liquid, always trying to minimise the surface area. For a curved surface, this inward pull creates a pressure difference — the concave side always has higher pressure.
The critical distinction: a liquid drop has one surface (liquid-air), giving . A soap bubble has two surfaces (outer air-soap and inner soap-air), giving . A bubble inside a liquid (like an air bubble in water) also has one surface, so it follows the formula.
Alternative Method — Energy approach
For a soap bubble expanding by : work done by excess pressure = increase in surface energy.
💡 Expert Tip
Quick memory aid: Drop = 2T/R, Bubble = 4T/R. The soap bubble formula has the extra factor of 2 because of two surfaces. If the question says "air bubble in water," use (only one surface). NEET loves testing this distinction.
Common Mistake
⚠️ Common Mistake
The most common error: using for a soap bubble. Students forget that a soap bubble is a thin film with two surfaces. A liquid drop in air has one surface (). A soap bubble in air has two surfaces (). An air bubble inside a liquid has one surface (). Always count the number of free surfaces before writing the formula.